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Robert Pires
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 14 buts |
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| 11-05-2008 | 21:00 | Villarreal - Espanyol Barcelone | 1 x |
| 21-10-2008 | 20:45 | Villarreal - AaB Alborg | 1 x |
| 01-11-2008 | 20:00 | Athletic Bilbao - Villarreal | 1 x |
| 06-12-2008 | 20:00 | Villarreal - Getafe | 1 x |
| 16-05-2009 | 22:00 | Villarreal - Real Madrid | 1 x |
| 07-08-2009 | 20:45 | Juventus de Turin - Villarreal | 2 x |
| 18-10-2009 | 17:00 | Xerez - Villarreal | 1 x |
| 29-10-2009 | 21:00 | UD Puertollano - Villarreal | 1 x |
| 01-11-2009 | 17:00 | Villarreal - Tenerife | 1 x |
| 05-11-2009 | 21:05 | Villarreal - Lazio Rome | 1 x |
| 08-11-2009 | 21:00 | FC Séville - Villarreal | 1 x |
| 28-03-2010 | 19:00 | Villarreal - FC Séville | 1 x |
| 29-01-2011 | 14:00 | Aston Villa - Blackburn Rovers | 1 x |
 2 pénaltys |
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| 13-08-2009 | 21:00 | Villarreal - Genoa | 1 x |
| 05-11-2009 | 21:05 | Villarreal - Lazio Rome | 1 x |
 7 cartons jaunes |
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| 04-10-2008 | 20:00 | Villarreal - Betis Séville | 1 x |
| 21-10-2008 | 20:45 | Villarreal - AaB Alborg | 1 x |
| 16-11-2008 | 17:00 | Malaga - Villarreal | 1 x |
| 04-04-2009 | 20:00 | Almeria - Villarreal | 1 x |
| 27-09-2009 | 21:00 | Deportivo La Corogne - Villarreal | 1 x |
| 28-11-2009 | 18:00 | Sporting Gijon - Villarreal | 1 x |
| 13-04-2010 | 22:00 | Getafe - Villarreal | 1 x |
 1 carton rouge après un carton jaune |
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| 04-04-2009 | 20:00 | Almeria - Villarreal | 1 x |